The postconf output is below. I have since found the solution to the problem, by simply entering the email address of the relay recipient on the forward to box below the alias entry, so Im sorry for that. When I first set them up on the old machine I don't remember having to do that, but I guess thats all the problem was.
[root@femail ~]# postconf -n
alias_database = hash:/etc/postfix/aliases
alias_maps = hash:/etc/postfix/aliases
allow_min_user = no
biff = no
bounce_queue_lifetime = 1d
broken_sasl_auth_clients = yes
command_directory = /usr/sbin
config_directory = /etc/postfix
content_filter = smtp-amavis:[127.0.0.1]:10024
daemon_directory = /usr/libexec/postfix
data_directory = /var/lib/postfix
debug_peer_level = 2
delay_warning_time = 0h
disable_vrfy_command = yes
enable_original_recipient = no
home_mailbox = Maildir/
html_directory = no
inet_interfaces = all
inet_protocols = ipv4
mail_owner = postfix
mailbox_command = /usr/libexec/dovecot/deliver
mailq_path = /usr/bin/mailq.postfix
manpage_directory = /usr/share/man
maximal_backoff_time = 4000s
maximal_queue_lifetime = 1d
message_size_limit = 15728640
minimal_backoff_time = 300s
mydestination = $myhostname, localhost, localhost.localdomain, localhost.$myhostname
mydomain = designsynthesis.net
myhostname = femail.designsynthesis.net
mynetworks = 127.0.0.0/8
mynetworks_style = subnet
myorigin = femail.designsynthesis.net
newaliases_path = /usr/bin/newaliases.postfix
proxy_read_maps = $canonical_maps $lmtp_generic_maps $local_recipient_maps $mydestination $mynetworks $recipient_bcc_maps $recipient_canonical_maps $relay_domains $relay_recipient_maps $relocated_maps $sender_bcc_maps $sender_canonical_maps $smtp_generic_maps $smtpd_sender_login_maps $transport_maps $virtual_alias_domains $virtual_alias_maps $virtual_mailbox_domains $virtual_mailbox_maps $smtpd_sender_restrictions
queue_directory = /var/spool/postfix
queue_run_delay = 300s
readme_directory = /usr/share/doc/postfix-2.5.9/README_FILES
recipient_bcc_maps = proxy:ldap:/etc/postfix/ldap/recipient_bcc_maps_domain.cf, proxy:ldap:/etc/postfix/ldap/recipient_bcc_maps_user.cf
recipient_delimiter = +
relay_domains = $mydestination, proxy:ldap:/etc/postfix/ldap/relay_domains.cf
sample_directory = /usr/share/doc/postfix-2.5.9/samples
sender_bcc_maps = proxy:ldap:/etc/postfix/ldap/sender_bcc_maps_domain.cf, proxy:ldap:/etc/postfix/ldap/sender_bcc_maps_user.cf
sendmail_path = /usr/sbin/sendmail.postfix
setgid_group = postdrop
smtp_data_init_timeout = 240s
smtp_data_xfer_timeout = 600s
smtpd_data_restrictions = reject_unauth_pipelining
smtpd_enforce_tls = no
smtpd_helo_required = yes
smtpd_helo_restrictions = permit_mynetworks,permit_sasl_authenticated, check_helo_access pcre:/etc/postfix/helo_access.pcre
smtpd_recipient_restrictions = reject_unknown_sender_domain, reject_unknown_recipient_domain, reject_non_fqdn_sender, reject_non_fqdn_recipient, reject_unlisted_recipient, check_policy_service inet:127.0.0.1:7777, permit_mynetworks, permit_sasl_authenticated, reject_unauth_destination, reject_non_fqdn_helo_hostname, reject_invalid_helo_hostname, check_policy_service inet:127.0.0.1:10031
smtpd_reject_unlisted_recipient = yes
smtpd_reject_unlisted_sender = yes
smtpd_sasl_auth_enable = yes
smtpd_sasl_authenticated_header = no
smtpd_sasl_local_domain =
smtpd_sasl_path = ./dovecot-auth
smtpd_sasl_security_options = noanonymous
smtpd_sasl_type = dovecot
smtpd_sender_login_maps = proxy:ldap:/etc/postfix/ldap/sender_login_maps.cf
smtpd_sender_restrictions = permit_mynetworks, reject_sender_login_mismatch, permit_sasl_authenticated
smtpd_tls_CAfile = /etc/pki/tls/certs/iRedMail_CA.pem
smtpd_tls_cert_file = /etc/pki/tls/certs/iRedMail_CA.pem
smtpd_tls_key_file = /etc/pki/tls/private/iRedMail.key
smtpd_tls_loglevel = 0
smtpd_tls_security_level = may
tls_random_source = dev:/dev/urandom
transport_maps = proxy:ldap:/etc/postfix/ldap/transport_maps_user.cf, proxy:ldap:/etc/postfix/ldap/transport_maps_domain.cf
unknown_local_recipient_reject_code = 550
virtual_alias_domains =
virtual_alias_maps = proxy:ldap:/etc/postfix/ldap/virtual_alias_maps.cf, proxy:ldap:/etc/postfix/ldap/virtual_group_maps.cf, proxy:ldap:/etc/postfix/ldap/sender_login_maps.cf, proxy:ldap:/etc/postfix/ldap/catchall_maps.cf
virtual_gid_maps = static:500
virtual_mailbox_base = /var/vmail
virtual_mailbox_domains = proxy:ldap:/etc/postfix/ldap/virtual_mailbox_domains.cf
virtual_mailbox_maps = proxy:ldap:/etc/postfix/ldap/virtual_mailbox_maps.cf
virtual_minimum_uid = 500
virtual_transport = dovecot
virtual_uid_maps = static:500
[root@femail ~]#